Optimization of spectral and angular selectivity in obliquely deposited tio2/ag/tio2 thin films prepared by thermal evaporation and sputtering methods

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Date
2014
Journal Title
Journal ISSN
Volume Title
Publisher
University of Dar es Salaam
Abstract
The present study advances prior knowledge and efforts in search of practical solar control windows. Optical properties of obliquely deposited TiO2/Ag/TiO2 multilayered films prepared by thermal evaporation and sputtering methods were investigated for energy efficiency of architectural and automobile windows. Investigation on the influency of layer thickness on the properties of TiO2 / Ag / TiO2 films yield an optimum layer thickness of 5 nm / 14 nm / 5 nm and 10 nm / 14 nm / 10 nm for optimal solar control performance of TiO2 / Ag / TiO2 films deposited by sputtering and thermal evaporation methods. The optimum films were then obliquely deposited with deposition angle varying from 0o to 70o for the purpose of optimizing angular selectivity of the films. The spectral transmittances were measured by HITACHI model U-2000 double beam UV-VIS-Spectrophotometer. The optimum thickness provided a peak transmittance of 70 % at a wavelength of 400 nm for near normal thermally evaporated thin films, and 72 % for films deposited by sputtering unit at ~ 320o C for TiO2 layers. Influence of deposition angle for obliquely deposited thin films was investigated for both sputtered and thermal evaporated thin films. The transmittance values for the films deposited by both methods gradually increased with increasing deposition angles to a peak of 80 % at 400 nm wavelength. The angular transmittance measurements were taken for the optimum films with 10 nm / 14 nm / 10 nm thicknesses due to relatively larger overall film thickness as compared to 5 nm / 14 nm / 5 nm. Films deposited at 30o, 40o and 60o, with incident light angle of ± 10o, ±30o, ±50o and ± 70o were used for transmittance measurements. Best angular performance of 7 % was realized at ±10o light incidence angle for films prepared at 60 o deposition angle.
Description
Available in print form, East Africana Collection, Dr. Wilbert Chagula Library, Class mark ( THS EAF QC176.8.O6H3)
Keywords
Thin films, Optical properties, Tanzania
Citation
Haji, H.F.(2014) Optimization of spectral and angular selectivity in obliquely deposited tio2/ag/tio2 thin films prepared by thermal evaporation and sputtering methods, Master dissertation, University of Dar es Salaam, Dar es Salaam